[Disc 1]
- Commentary (audio) Director & Cast Filmmakers`
- Bloopers
- Galleries
- Music Video : "Signal Fire" by Snow Patorl
- Previews

[Disc 2]
- Grains of Sand : Building Sandman
- Re-Imagining the Goblin
- Covered in Black : Creating Venom
- Hanging On... : Gwen Stacy and the Collapsing floor
- Fighting, Flying and Driving : The Stunts
- Tangled Web : The love traingles of Spider-Man 3
- Wall of Paper
- Inside the Editing Room
- The Science of Sound
- New York : From rooftops to backstreets
- Cleveland : The Chase on Euclid avenue
- And More!

Peter Parker has finally managed to piece together the once-broken parts of
his life, maintaining a balance between his relationship with Mary-Jane and
his responsibility as Spider-Man. But more challenges arise for our young
hero. Peter's old friend Harry Obsourne has set out for revenge against Peter;
taking up the mantle of his late father's persona as The New Goblin, and
Peter must also capture Uncle Ben's real killer, Flint Marko, who has been
transformed into his toughest foe yet, the Sandman. All hope seems lost
when suddenly Peter's suit turns jet-black and greatly amplifies his powers.
But it also begins to greatly amplify the much darker qualities of Peter's
personality that he begins to lose himself to. Peter has to reach deep inside
himself to free the compassionate hero he used to be if he is to ever conquer
the darkness within and face not only his greatest enemies, but
also...himself.